H2N2V1, France, Analysis, bibRecord, 000275

Synthesis and crystal structure of (1,6-NH3C6H12NH3)2(1-NH3C10H7)2P6O18.2H2O

Identifieur interne : 000275 ( France/Analysis ); précédent : 000274; suivant : 000276

Synthesis and crystal structure of (1,6-NH3C6H12NH3)2(1-NH3C10H7)2P6O18.2H2O

Auteurs : H. Marouani [France] ; M. Rzaigui [France] ; M. Bagieu-Beucher [France]

Source :

European Journal of Solid State and Inorganic Chemistry [ 0992-4361 ] ; 1998.

RBID : ISTEX:495733B191B31BE3984BD53127DC01F942B78A1C

English descriptors

Teeft :
- Anion, Aqueous solution, Atomic arrangement, Bond angles, Bond distances, Chem, Crystal chemistry, Crystal structure, Cyclohexaphosphoric acid, Final results, Hydrogen atoms, Hydrogen bonds, Independent reflections, Inorg, Intensity data collection, Main interatomic distances, Marouani, Organic groups, Other atoms, Powder diffraction, Ring anions, Room temperature, Solid state chem, Solid state inorg, Space group, Structure determination, Tetrahedral representation, Tetrahedron, Thermal analysis, Title compound, Unit cell, Unit cell parameters, Water molecules.

Abstract

Abstract: Synthesis and complete structural characterization by X-ray diffraction, DTA, GTA and IR are given for a new cyclohexaphosphate: (1,6-NH3C6H12NH3)2 (1-NH3C10H7)2P6O18.2H2O. This compound is monoclinic P21/c with the following unit-cell parameters: a = 11.861(2)Å, b = 10.104(1)Å, c = 19.664(6)Å, β = 96.44(2)°, and Z = 2. The crystal structure has been solved and refined to R = 0.033 using 3928 independent reflections. The atomic arrangement can be described as layer organisation. Layers built by P6O18 ring anions and water molecules spread in the plans (100). Between these layers are located the organic groups which form hydrogen bonds with oxygen atoms of P6O18 rings and water molecules. Geometrical characteristics of hydrogen bonds are described. The reported IR study is supported by a delaited theoretical group analysis applied to P6O18 with D6h ideal local symmetry.

Url:

https://api.istex.fr/ark:/67375/6H6-D1X23HQ8-L/fulltext.pdf

DOI: 10.1016/S0992-4361(98)80023-4

Affiliations:

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Le document en format XML

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<front><div type="abstract" xml:lang="en">Abstract: Synthesis and complete structural characterization by X-ray diffraction, DTA, GTA and IR are given for a new cyclohexaphosphate: (1,6-NH3C6H12NH3)2 (1-NH3C10H7)2P6O18.2H2O. This compound is monoclinic P21/c with the following unit-cell parameters: a = 11.861(2)Å, b = 10.104(1)Å, c = 19.664(6)Å, β = 96.44(2)°, and Z = 2. The crystal structure has been solved and refined to R = 0.033 using 3928 independent reflections. The atomic arrangement can be described as layer organisation. Layers built by P6O18 ring anions and water molecules spread in the plans (100). Between these layers are located the organic groups which form hydrogen bonds with oxygen atoms of P6O18 rings and water molecules. Geometrical characteristics of hydrogen bonds are described. The reported IR study is supported by a delaited theoretical group analysis applied to P6O18 with D6h ideal local symmetry.</div>
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Synthesis and crystal structure of (1,6-NH3C6H12NH3)2(1-NH3C10H7)2P6O18.2H2O

Synthesis and crystal structure of (1,6-NH3C6H12NH3)2(1-NH3C10H7)2P6O18.2H2O

Source :

English descriptors

Abstract

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